Place the chai tea bag into a mason jar. In a small saucepan over medium-high heat, warm the whole milk, stirring constantly, until it begins to boil. Pour the boiling milk over the chai tea bag in the mason jar and let steep for 15 minutes before removing the tea bag. Allow the mixture to cool completely to room temperature before moving on.
Preheat the oven to 350°F (177ºC), then line a standard cupcake pan with paper liners.
In a medium bowl, add the cake flour, baking powder, 2 teaspoons of the chai spice mix, and salt. Whisk to combine and set aside.
In the bowl of your stand mixer fitted with the paddle attachment (or with a handheld mixer and large bowl), cream the butter and sugar together on medium-high speed until light and fluffy, 3-4 minutes, scraping down the bowl and paddle as needed. Turn the mixer to low speed and mix in the egg and egg white until combined, then add vanilla and sour cream and mix for one minute on high speed, scraping down the bowl and paddle once more.
Turn the mixer off and add in the dry ingredients all at once. Turn the mixer to low speed mix until the flour mixture just starts to combine, then add the (room temperature!) chai milk mixture slowly and mix until incorporated, about 30 seconds more. Scrape down the sides and bottom of the bowl and give it a few stirs to make sure there are no lumps (without over-mixing). The batter will be slightly thick.
Scoop the batter into the lined cupcake pan and fill each liner no more than 2/3 full, then bake for 14-18 minutes. They're done when they spring back to the touch and a toothpick inserted into the middle comes out clean. Let the cupcakes cool completely before frosting.